Influence of ligand substitution at the donor and acceptor center on MMCT in a cyanide-bridged mixed-valence system
Author:
Affiliation:
1. State Key Laboratory of Structural Chemistry
2. Fujian Institute of Research on the Structure of Matter
3. Chinese Academy of Sciences
4. Fuzhou
5. China
Abstract
A series of cyanide-bridged complexes [TpmRu(LD)(μ-CN)Ru(LP)Cp*][PF6]2 were investigated by changing the substitutions of the donor and acceptor sites to systemically tune MMCT.
Funder
National Natural Science Foundation of China
Chinese Academy of Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01303B
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