First synthesis of heterocyclic allenes – benzazecine derivatives

Author:

Voskressensky Leonid G.1234ORCID,Titov Alexander A.1234,Dzhankaziev Maksad S.1234,Borisova Tatiana N.1234,Kobzev Maxim S.1234,Dorovatovskii Pavel V.564,Khrustalev Victor N.12347,Aksenov Alexander V.894ORCID,Varlamov Alexey V.1234

Affiliation:

1. Organic Chemistry Department

2. Peoples' Friendship University of Russia

3. Moscow 117198

4. Russia

5. National Research Center “Kurchatov Institute”

6. Moscow 123182

7. Nesmeyanov Institute of Organoelement Compounds of RAS

8. North-Caucasus Federal University

9. Stavropol 355009

Abstract

Benzazecines with an allene fragment were prepared for the first time and in high yields via tandem reaction of 1-phenylethynyl-1-methyl(benzyl)-1,2,3,4-tetrahydroisoquinolines with activated alkynes in trifluoroethanol.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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