Cu(ii) inhibited the transport of tetracycline in porous media: role of complexation

Author:

Xu Chang12,Gong Bo12,Zhao Shan12,Sun Xiao-Min3ORCID,Wang Shu-Guang1245ORCID,Song Chao12ORCID

Affiliation:

1. Shandong Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Shandong University, Qingdao, Shandong, 266237, China

2. Shandong Key Laboratory of Environmental Processes and Health, School of Environmental Science and Engineering, Shandong University, Qingdao, Shandong, 266237, China

3. Environment Research Institute, Shandong University, Qingdao 266237, China

4. Sino-French Research Institute for Ecology and Environment (ISFREE), School of Environmental Science and Engineering, Shandong University, Qingdao, Shandong, 266237, China

5. WeiHai Research Institute of Industrial Technology of Shandong University, Weihai, 264209, China

Abstract

The coexisting Cu(ii) inhibited the transport of tetracycline in the quartz sand mainly via electrostatic force and complexation. Strong van der Waals forces and coordination bonds between complexes and SiO2 lead to high adsorption energy.

Funder

National Natural Science Foundation of China

Taishan Scholar Project of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

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