Tuning regioselective oxidation toward phenol via atomically dispersed iron sites on carbon

Author:

Ding Yuxiao12345,Zhang Pengfei4567ORCID,Xiong Hailong891011,Sun Xiaoyan1231213,Klyushin Alexander14153ORCID,Zhang Bingsen16171811ORCID,Liu Zigeng1920213ORCID,Zhang Jinshui4567ORCID,Zhu Huiyuan4567ORCID,Qiao Zhen-An891011ORCID,Heumann Saskia123ORCID,Dai Sheng4567ORCID

Affiliation:

1. Max Planck Institute for Chemical Energy Conversion

2. Mülheim an der Ruhr 45470

3. Germany

4. Chemical Science Division

5. Oak Ridge National Laboratory

6. Oak Ridge

7. USA

8. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry

9. Jilin University

10. Changchun 130012

11. China

12. Institut für Chemie

13. Technische Universität Berlin

14. Fritz-Haber-Institut der Max-Planck Gesellschaft

15. Berlin 14195

16. Institute of Metal Research

17. Chinese Academy of Sciences

18. Shenyang 110016

19. Institute of Energy and Climate Research

20. Forschungzentrum Jülich GmbH

21. Jülich 52425

Abstract

Inspired by iron enzymes exhibiting a high level of selectivity in hydrocarbon oxidation reactions, a biomimetic iron-based heterogeneous catalyst is developed to achieve remarkable activity and unprecedented selectivity toward phenol oxidation.

Funder

Max-Planck-Gesellschaft

National Natural Science Foundation of China

Ministry of Education of the People's Republic of China

Program for Jilin University Science and Technology Innovative Research Team

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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