Reverse regioselectivity in Pd(0)/InI-mediated allylation of aldehydes with ε-amido-allylindiums generated from β-lactams. A new entry to non-racemic highly substituted γ-butyrolactones-Reference-Cited by-同舟云学术

Reverse regioselectivity in Pd(0)/InI-mediated allylation of aldehydes with ε-amido-allylindiums generated from β-lactams. A new entry to non-racemic highly substituted γ-butyrolactones

Published:2016 Issue:31 Volume:6 Page:26451-26460
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Klimczak Urszula¹²³⁴,Staszewska-Krajewska Olga¹²³⁴,Zambroń Bartosz K.¹²³⁴

Affiliation:

1. Institute of Organic Chemistry

2. Polish Academy of Sciences

3. 01-224 Warsaw

4. Poland

Abstract

ε-Amido-allylindiums generated from β-lactams in the presence of 2 eq. of InI, catalytic amounts of Pd(PPh₃)₄ and 5 eq. of CF₃CO₂H react with a number of aromatic and aliphatic aldehydes to afford trisubstituted γ-butyrolactones in high yield.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA00517A

Reference37 articles.

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