{NiII8LnIII6} (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour-Reference-Cited by-同舟云学术

{NiII8LnIII6} (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour

Published:2016 Issue:20 Volume:45 Page:8566-8572
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Guarda Eliana¹²³⁴⁵,Bader Katharina⁶⁷⁸⁹,van Slageren Joris⁶⁷⁸⁹,Alborés Pablo¹²³⁴⁵

Affiliation:

1. Departamento de Química Inorgánica

2. Analítica y Química Física/INQUIMAE (CONICET)

3. Facultad de Ciencias Exactas y Naturales Universidad de Buenos Aires

4. C1428EHA Buenos Aires

5. Argentina

6. Institut für Physikalische Chemie

7. Universität Stuttgart

8. Stuttgart

9. Germany

Abstract

We prepared through CO₂ air fixation novel Ni₈Ln₆ complexes showing a remarkable μ₅-carbonate bridged octanuclear planar {Ni₄Ln₄} core and unusual MCE behaviour.

Funder

Deutsche Forschungsgemeinschaft

Universidad de Buenos Aires

Agencia Nacional de Promoción Científica y Tecnológica

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00859C

Reference26 articles.

1. CO2 as a reaction ingredient for the construction of metal cages: a carbonate-panelled [Gd6Cu3] tridiminished icosahedron