Postsynthetic modifications of [2,2,2-(H)(PPh3)2-closo-2,1-RhSB8H8] with Lewis bases: cluster modular tuning-Reference-Cited by-同舟云学术

Postsynthetic modifications of [2,2,2-(H)(PPh3)2-closo-2,1-RhSB8H8] with Lewis bases: cluster modular tuning

Published:2016 Issue:20 Volume:45 Page:8622-8636
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Luaces Susana¹²³⁴⁵,Passarelli Vincenzo¹²³⁴⁵,Artigas María José¹²³⁴⁵,Lahoz Fernando J.¹²³⁴⁵,Oro Luis A.¹²³⁴⁵,Macías Ramón¹²³⁴⁵

Affiliation:

1. Departamento de Química Inorgánica

2. Instituto de Síntesis Química y Catálisis Homogénea (ISQCH)

3. Universidad de Zaragoza-CSIC

4. ES-50009 Zaragoza

5. Spain

Abstract

Reaction of a closo-hydridorhodathiaborane with Lewis bases is a convenient postsynthetic approach for tailoring the reactivity of metallathiaboranes that combine rhodium centers and hydride ligands within a flexible deltahedral framework.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00856A

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