Slow magnetic relaxation in a homoaxially phosphine oxide coordinated pentagonal bipyramidal Dy(iii) complex

Author:

Kalita Pankaj1ORCID,Ahmed Naushad1ORCID,Moorthy Shruti2ORCID,Béreau Virginie34ORCID,Bar Arun Kumar5ORCID,Kumar Pawan6,Nayak Prakash7ORCID,Sutter Jean-Pascal3ORCID,Singh Saurabh Kumar2ORCID,Chandrasekhar Vadapalli16ORCID

Affiliation:

1. Tata Institute of Fundamental Research, 36/P, Gopanpally Village, Serilingampally Mandal, Ranga Reddy District, Hyderabad 500046, India

2. Department of Chemistry, Indian Institute of Technology Hyderabad, Kandi, Sangareddy, 502284, Telangana, India

3. Laboratoire de Chimie de Coordination du CNRS, Université de Toulouse, CNRS, Toulouse, France

4. Université de Toulouse, Institut Universitaire de Technologie Paul Sabatier-Département de Chimie, Av. Georges Pompidou, F-81104 Castres, France

5. Department of Chemistry, Indian Institute of Science Education and Research (IISER) Tirupati, Tirupati, Andhra Pradesh 501507, India

6. Department of Chemistry, IIT Kanpur, Kanpur 208016, India

7. School of Chemical Sciences, National Institute of Science Education and Research, HBNI, Bhubaneswar 752050, India

Abstract

Synthesis, structural characterization and combined experimental and theoretical magnetic properties of a new homoaxially phosphine oxide coordinated pentagonal bipyramidal complex, [(LN3O2Ph)DyIII(Cy3PO)2]·[BPh4] are reported.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

Tata Institute of Fundamental Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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