Quantitative temporally and spatially resolved X-ray fluorescence microprobe characterization of the manganese dissolution-deposition mechanism in aqueous Zn/α-MnO2 batteries-Reference-Cited by-同舟云学术

Quantitative temporally and spatially resolved X-ray fluorescence microprobe characterization of the manganese dissolution-deposition mechanism in aqueous Zn/α-MnO2 batteries

Published:2020 Issue:11 Volume:13 Page:4322-4333
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Wu Daren¹²³⁴⁵^ORCID,Housel Lisa M.¹²³⁴⁵^ORCID,Kim Sung Joo⁶⁷⁸⁹⁵^ORCID,Sadique Nahian¹⁰¹¹⁴⁵^ORCID,Quilty Calvin D.¹⁰¹¹⁴⁵^ORCID,Wu Lijun¹²⁸⁹⁵,Tappero Ryan¹³⁷⁸⁹⁵^ORCID,Nicholas Sarah L.¹³⁷⁸⁹⁵,Ehrlich Steven¹³⁷⁸⁹⁵,Zhu Yimei¹²⁸⁹⁵¹⁴,Marschilok Amy C.¹²³⁴⁵^ORCID,Takeuchi Esther S.¹²³⁴⁵^ORCID,Bock David C.⁶⁷⁸⁹⁵^ORCID,Takeuchi Kenneth J.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Materials Science and Chemical Engineering

2. Stony Brook University

3. Stony Brook

4. New York 11794

5. USA

6. Energy and Photon Sciences Directorate

7. Brookhaven National Laboratory

8. Upton

9. New York 11973

10. Department of Chemistry

11. Stony Brook University, Stony Brook

12. Condensed Matter Physics and Materials Science Department, Brookhaven National Laboratory

13. National Synchrotron Light Source II

14. Department of Physics and Astronomy

Abstract

Operando, spatiotemporal resolved synchrotron X-ray fluorescence mapping measurements on a custom aqueous Zn/α-MnO₂ cell provided direct, quantitative evidence of a Mn dissolution-deposition faradaic mechanism that governs the electrochemistry.

Funder

Basic Energy Sciences

Office of Electricity Delivery and Energy Reliability

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/EE/D0EE02168G

Reference63 articles.

1. Holy Grails in Chemistry: Investigating and Understanding Fast Electron/Cation Coupled Transport within Inorganic Ionic Matrices

2. Review of electrical energy storage technologies, materials and systems: challenges and prospects for large-scale grid storage