Retro-Diels–Alder decomposition of norbornadiene mediated by a cationic magnesium complex-Reference-Cited by-同舟云学术

Retro-Diels–Alder decomposition of norbornadiene mediated by a cationic magnesium complex

Published:2021 Issue:43 Volume:57 Page:5278-5281
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Thum Katharina¹²³⁴⁵,Pahl Jürgen¹²³⁴⁵,Eyselein Jonathan¹²³⁴⁵,Elsen Holger¹²³⁴⁵,Langer Jens¹²³⁴⁵^ORCID,Harder Sjoerd¹²³⁴⁵^ORCID

Affiliation:

1. Inorganic and Metallorganic Chemistry

2. Universität Erlangen-Nürnberg

3. Egerlandstrasse 1

4. Erlangen 91058

5. Germany

Abstract

The addition of norbornadiene to a “naked” cationic β-diketiminate magnesium complex gave first evidence for Mg–norbornadiene coordination. Complexation results in the facile retro-Diels–Alder decomposition of norbornadiene at room temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC01691A

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