Retro-Diels–Alder decomposition of norbornadiene mediated by a cationic magnesium complex

Author:

Thum Katharina12345,Pahl Jürgen12345,Eyselein Jonathan12345,Elsen Holger12345,Langer Jens12345ORCID,Harder Sjoerd12345ORCID

Affiliation:

1. Inorganic and Metallorganic Chemistry

2. Universität Erlangen-Nürnberg

3. Egerlandstrasse 1

4. Erlangen 91058

5. Germany

Abstract

The addition of norbornadiene to a “naked” cationic β-diketiminate magnesium complex gave first evidence for Mg–norbornadiene coordination. Complexation results in the facile retro-Diels–Alder decomposition of norbornadiene at room temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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1. Chemistry with weakly coordinating aluminates [Al(ORF)4]− and borates [B(ORF)4]−: From fundamentals to application;Comprehensive Inorganic Chemistry III;2023

2. Low‐valent Mg(I) complexes by ball‐milling;Zeitschrift für anorganische und allgemeine Chemie;2022-05-13

3. Organometallic Complexes of the Alkaline Earth Metals;Comprehensive Organometallic Chemistry IV;2022

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