Isolation of single crystals of a homoleptic UO22+-diglycolamide complex from a room temperature ionic liquid: X-ray crystallography and complexation studies

Author:

Ansari Seraj A.1ORCID,Wadawale Amey P.2,Verboom Willem3ORCID,Mohapatra Prasanta K.1ORCID

Affiliation:

1. Radiochemistry Division, Bhabha Atomic Research Centre, Mumbai–400 085, India

2. Chemistry Division, Bhabha Atomic Research Centre, Mumbai–400 085, India

3. Molecular Nanofabrication Group, Department of Molecules & Materials, MESA+Institute for Nanotechnology, University of Twente, P.O. Box 217, Enschede 7500 AE, The Netherlands

Abstract

Complexation and structural investigations of the solid complex of UO22+ ion and TMDGA isolated from an ionic liquid for the first time revealed that the nature and structural features of the complex are identical with those of the complex isolated from the aqueous medium.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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