Exploring the reversible host–guest chemistry of a crystalline octanuclear Ag(i) metallosupramolecular macrocycle formed from a simple pyrazinylpyridine ligand

Author:

Dalton Hannah L.12345,Lynes Amy D.12345,Twamley Brendan67845,Byrne Kevin92345,Schmitt Wolfgang92345ORCID,Hawes Chris S.10111213ORCID,Gunnlaugsson Thorfinnur12345ORCID

Affiliation:

1. School of Chemistry and Trinity Biomedical Sciences Institute

2. The University of Dublin

3. Trinity College Dublin

4. Dublin 2

5. Ireland

6. School of Chemistry

7. University of Dublin

8. Trinity College

9. School of Chemistry and Centre for Research on Adaptive Nanostructures and Nanodevices

10. School of Chemical and Physical Sciences

11. Keele University

12. Keele ST5 5BG

13. UK

Abstract

High nuclearity Ag(i) assemblies are prepared from simple polytopic ligands, including an octanuclear metallomacrocycle which exhibits reversible and selective guest exchange.

Funder

Science Foundation Ireland

Irish Research Council

H2020 European Research Council

Trinity College Dublin

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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