Ligand-induced decarbonylation in diphosphine-ligated palladium acetates [CH3CO2Pd((PR2)2CH2)]+ (R = Me and Ph)-Reference-Cited by-同舟云学术

Ligand-induced decarbonylation in diphosphine-ligated palladium acetates [CH3CO2Pd((PR2)2CH2)]+ (R = Me and Ph)

Published:2018 Issue:4 Volume:54 Page:346-349
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Lesslie Michael¹²³⁴⁵,Yang Yang⁶⁷⁸⁹¹⁰,Canty Allan J.¹¹¹²¹³¹⁰^ORCID,Piacentino Elettra¹²³⁴⁵,Berthias Francis¹⁴¹⁵¹⁶¹⁷¹⁸,Maitre Philippe¹⁴¹⁵¹⁶¹⁷¹⁸^ORCID,Ryzhov Victor¹²³⁴⁵^ORCID,O'Hair Richard A. J.⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. and Center for Biochemical and Biophysical Sciences

3. Northern Illinois University

4. DeKalb

5. USA

6. School of Chemistry

7. Bio21 Institute of Molecular Science and Biotechnology

8. The University of Melbourne

9. Victoria 3010

10. Australia

11. School of Physical Sciences

12. University of Tasmania

13. Hobart

14. Laboratoire de Chimie Physique

15. Bâtiment 349

16. Université Paris-Sud

17. CNRS

18. Université Paris-Saclay

Abstract

Isotope labelling, IR spectroscopy and DFT calculations reveal a novel ligand-induced decarbonylation reaction.

Funder

Australian Research Council

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C7CC08944A

Reference31 articles.

1. R. A. J. O’Hair , “Gas Phase Ligand Fragmentation to Unmask Reactive Metallic Species” , in “Reactive Intermediates. MS Investigations in Solution” , ed. L. S. Santos , Wiley-VCH , Weinheim , 2010 , ch. 6, p. 199 , ISBN: 978-3-527-32351-7

2. Gas Phase Studies of the Pesci Decarboxylation Reaction: Synthesis, Structure, and Unimolecular and Bimolecular Reactivity of Organometallic Ions

3. Role of the Metal, Ligand, and Alkyl/Aryl Group in the Hydrolysis Reactions of Group 10 Organometallic Cations [(L)M(R)]+

4. Direct versus Water-Mediated Protodecarboxylation of Acetic Acid Catalyzed by Group 10 Carboxylates, [(phen)M(O2CCH3)]+

5. Decarboxylative-Coupling of Allyl Acetate Catalyzed by Group 10 Organometallics, [(phen)M(CH3)]+

Cited by 17 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Decarboxylation of fatty acids by ternary zinc cationic complexes studied by mass spectrometry and theoretical calculations;International Journal of Mass Spectrometry;2024-05

2. Palladium-mediated CO2 extrusion followed by insertion of ketenes: translating mechanistic studies to develop a one-pot method for the synthesis of ketones;Australian Journal of Chemistry;2023-05-31

3. Bringing a Mechanistic Lens to the Development of New Transfer Hydroarylation Isodesmic Reactions for the Synthesis of Amides, Thioamides, Amidines, Alkenes and Ketones from Carboxylic Acids via Extrusion and Insertion Elementary Steps;Israel Journal of Chemistry;2023-05-25

4. Modeling Metal-Catalyzed Polyethylene Depolymerization: [(Phen)Pd(X)]+ (X = H and CH3) Catalyze the Decomposition of Hexane into a Mixture of Alkenes via a Complex Reaction Network;Organometallics;2021-02-09

5. A Two-Step Catalytic Cycle for the Acceptorless Dehydrogenation of Ethane by Group 10 Metal Complexes: Role of the Metal in Reactivity and Selectivity;Organometallics;2020-11-13