An efficient method to prepare supported bismuth nanoparticles as highly selective electrocatalyst for the conversion of CO2 into formate

Author:

Miola Matteo12345ORCID,de Jong Bart C. A.12345ORCID,Pescarmona Paolo P.12345ORCID

Affiliation:

1. Chemical Engineering Group

2. Engineering and Technology Institute Groningen

3. University of Groningen

4. 9747 AG Groningen

5. The Netherlands

Abstract

We report a novel and upscalable method to synthesise small, highly dispersed Bi nanoparticles on activated carbon. This electrocatalyst displays outstanding selectivity (FE > 99% at −1.07 V vs. RHE) and stability in the conversion of CO2 to formate.

Funder

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference31 articles.

1. IPCC–Intergovernmental Panel on Climate Change 2014: Synthesis Report, 2015

2. NASA–National Aeronautics and Space Administration, https://climate.nasa.gov/

3. Combining theory and experiment in electrocatalysis: Insights into materials design

4. Electrochemical CO 2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design

5. BASF, http://formic-acid.basf.us/p02/USWeb-Internet/formic-acid/en_GB/

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