Insight into the thermal decomposition of ammonium hexahalogenoiridates(iv) and hexachloroiridate(iii)-Reference-Cited by-同舟云学术

Insight into the thermal decomposition of ammonium hexahalogenoiridates(iv) and hexachloroiridate(iii)

Published:2020 Issue:40 Volume:22 Page:22923-22934
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Yusenko Kirill V.¹²³^ORCID,Zvereva Valentina V.⁴⁵⁶^ORCID,Martynova Svetlana A.⁴⁵⁶,Asanov Igor P.⁴⁵⁶,La Fontaine Camille⁷⁸⁹¹⁰^ORCID,Roudenko Olga⁷⁸⁹¹⁰,Gubanov Alexander I.⁴⁵⁶^ORCID,Plyusnin Pavel E.⁴⁵⁶^ORCID,Korenev Sergey V.⁴⁵⁶,Asanova Tatyana I.⁴⁵⁶^ORCID

Affiliation:

1. BAM Federal Institute for Materials Research and Testing

2. D-12489 Berlin

3. Germany

4. Nikolaev Institute of Inorganic Chemistry

5. 630090 Novosibirsk

6. Russia

7. Synchrotron SOLEIL

8. Saint-Aubin

9. Gilf-sur-Yvette

10. France

Abstract

Decomposition of (NH₄)₃[IrCl₆]·H₂O, (NH₄)₂[IrCl₆] and (NH₄)₂[IrBr₆] has been studied. (NH₄)₂[Ir(NH₃)Cl₅] and (NH₄)₂[Ir(NH₃)Br₅] have been proposed as key intermediates in hydrogen flow. In the inert atmosphere, (NH₄)[Ir(NH₃)₂Cl₄] and (NH₄)[Ir(NH₃)₂Br₄] were found.

Funder

Russian Union of the Federal Republic of Israel

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP02743J

Reference30 articles.

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4. The ammonium ion and the ammine ligand as internal reducing agents for platinum-group-metal complexes