Sequential single-crystal-to-single-crystal transformations promoted by gradual thermal dehydration in a porous metavanadate hybrid

Author:

Martín-Caballero Jagoba123,Wéry Ana San José456,Artetxe Beñat78910,Reinoso Santiago78910,Felices Leire San118910,Vilas José Luis123128,Gutiérrez-Zorrilla Juan M.12378

Affiliation:

1. BCMaterials

2. Parque Tecnológico de Bizkaia

3. 48160 Derio, Spain

4. Departamento de Desarrollo Sostenible

5. Universidad Católica de Ávila

6. 05005 Ávila, Spain

7. Departamento de Química Inorgánica

8. Facultad de Ciencia y Tecnología

9. Universidad del País Vasco UPV/EHU

10. 48080 Bilbao, Spain

11. Servicios Generales de Investigación SGIker

12. Departamento de Química Física

Abstract

The porous hybrid metavanadate [{Cu(cyclam)}(VO3)2]·5H2O undergoes a series of sequential and reversible transformations upon thermally-triggered gradual dehydration that have been monitored by single-crystal X-ray diffraction.

Funder

Euskal Herriko Unibertsitatea

Eusko Jaurlaritza

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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