Alternating ring-opening copolymerization of epoxides with saturated and unsaturated cyclic anhydrides: reduced viscosity poly(propylene fumarate) oligomers for use in cDLP 3D printing-Reference-Cited by-同舟云学术

Alternating ring-opening copolymerization of epoxides with saturated and unsaturated cyclic anhydrides: reduced viscosity poly(propylene fumarate) oligomers for use in cDLP 3D printing

Published:2020 Issue:19 Volume:11 Page:3313-3321
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Shin Yongjun¹²³⁴⁵,Becker Matthew L.⁵⁶⁷⁸⁴^ORCID

Affiliation:

1. Department of Polymer Science

2. The University of Akron

3. Akron

4. USA

5. Department of Chemistry

6. Department of Mechanical Engineering & Materials Science, Department of Biomedical Engineering

7. Department of Orthopedic Surgery Duke University

8. Durham

Abstract

A ring-opening copolymerization of propylene oxide with saturated and unsaturated anhydrides using Mg(BHT)₂(THF)₂ catalyst followed by an isomerization yields poly(propylene fumarate) (PPF) oligomers with improved properties for 3D printing.

Funder

Ohio Department of Development

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2020/PY/D0PY00453G

Reference49 articles.

1. 3D Printing of Shape Memory Polymers for Flexible Electronic Devices

2. Polymers for 3D Printing and Customized Additive Manufacturing

3. Designing Biomaterials for 3D Printing