Cavity-catalyzed hydrogen transfer dynamics in an entangled molecular ensemble under vibrational strong coupling-Reference-Cited by-同舟云学术

Cavity-catalyzed hydrogen transfer dynamics in an entangled molecular ensemble under vibrational strong coupling

Published:2023 Issue:16 Volume:25 Page:11771-11779
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Fischer Eric W.¹^ORCID,Saalfrank Peter¹²^ORCID

Affiliation:

1. Theoretische Chemie, Institut für Chemie, Universität Potsdam, Karl-Liebknecht-Strasse 24-25, D-14476, Potsdam-Golm, Germany

2. Institut für Physik und Astronomie, Universität Potsdam, Karl-Liebknecht-Straße 24-25, D-14476, Potsdam-Golm, Germany

Abstract

Light-matter entanglement in a cavity-catalysed hydrogen transfer ensemble reaction model is studied, its relevance for thermal rate enhancement is discussed and entanglement-related deviations from reactive single-molecule models are analyzed.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP00175J

Reference41 articles.

1. Hybrid Light–Matter States in a Molecular and Material Science Perspective

2. Polariton chemistry: controlling molecular dynamics with optical cavities

3. Polaritonic Chemistry with Organic Molecules

4. Vibration-Cavity Polariton Chemistry and Dynamics

5. Polariton chemistry: Molecules in cavities and plasmonic media

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