Experimental and theoretical studies on the thermal decomposition of trans-1-chloro-3,3,3-trifluoropropene and 2-chloro-3,3,3-trifluoropropene and their fire-extinguishing performance-Reference-Cited by-同舟云学术

Experimental and theoretical studies on the thermal decomposition of trans-1-chloro-3,3,3-trifluoropropene and 2-chloro-3,3,3-trifluoropropene and their fire-extinguishing performance

Published:2020 Issue:30 Volume:44 Page:12932-12941
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Wu Rui¹²³⁴,Wang Xingyu¹²³⁴,Cheng Lu¹²³⁴,Ren Changxing⁵⁶⁷,Wei Xingyou⁸⁹¹⁰⁴,Zhang Xiao¹²³⁴^ORCID

Affiliation:

1. Key Laboratory of Civil Aviation Thermal Hazards Prevention and Emergency Response

2. Civil Aviation University of China

3. Tianjin 300300

4. P. R. China

5. National Center for Fire Engineering Technology

6. Tianjin 300381

7. China

8. Hulunbuir Air Traffic Management Station

9. CAAC

10. Hulunbuir

Abstract

trans-1-Chloro-3,3,3-trifluoropropene and 2-chloro-3,3,3-trifluoropropene have the potential to act as fire extinguishing agents, but their thermal decomposition mechanism and fire extinguishing performance have not been investigated.

Funder

National Natural Science Foundation of China

State Key Laboratory of Fire Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ02808H

Reference41 articles.

1. Atmospheric chemistry of t-CF3CHCHCl: products and mechanisms of the gas-phase reactions with chlorine atoms and hydroxyl radicals

2. OH + (E)- and (Z)-1-Chloro-3,3,3-trifluoropropene-1 (CF3CH═CHCl) Reaction Rate Coefficients: Stereoisomer-Dependent Reactivity