Divergent synthesis of unsymmetrical azobenzenes via Cu-catalyzed C–N coupling

Author:

Wang Yuzhou1,Xie Rongrong1,Huang Lingyu1,Tian Ya-Nan1,Lv Shihai1,Kong Xiangfei1,Li Shiqing1ORCID

Affiliation:

1. Guangxi Key Laboratory of Electrochemical and Magneto-Chemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China

Abstract

Efficient, one-pot, and low-cost metal-catalyzed tandem Chan–Lam coupling/deprotection and Ullmann/Chan–Lam/deprotection reactions to access unsymmetrical azobenzenes are disclosed.

Funder

National Natural Science Foundation of China

Specific Research Project of Guangxi for Research Bases and Talents

Natural Science Foundation of Guangxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference66 articles.

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2. K.Hunger , Industrial Dyes: Chemistry, Properties, Applications , Wiley-VCH , Weinheim (Germany) , 2003

3. Synthesis of azobenzenes: the coloured pieces of molecular materials

4. R. J.Chudgar and J.Oakes , Kirk-Othmer Encyclopedia of Chemical Technology , Wiley , New York , 1992

5. Activatable Cell Penetrating Peptide–Peptide Nucleic Acid Conjugate via Reduction of Azobenzene PEG Chains

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