Flux growth and phase diversity of the triple oxides of transition metals (Mn,Fe,Ga)2O3in multicomponent fluxes based on Bi2O3–MoO3–B2O3

Flux growth and phase diversity of the triple oxides of transition metals (Mn,Fe,Ga)₂O₃in multicomponent fluxes based on Bi₂O₃–MoO₃–B₂O₃–Na₂O

Published:2023 Issue:18 Volume:25 Page:2824-2834
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Moshkina Evgeniya¹^ORCID,Seryotkin Yurii²³,Bayukov Oleg¹,Molokeev Maxim¹⁴⁵^ORCID,Kokh Dieter⁶⁷,Smorodina Ekaterina⁴,Krylov Alexander¹^ORCID,Bezmaternykh Leonard¹

Affiliation:

1. Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia

2. Novosibirsk State University, 630090 Novosibirsk, Russia

3. Institute of Geology and Mineralogy, 630090 Novosibirsk, Russia

4. Siberian Federal University, 660041 Krasnoyarsk, Russia

5. Far Eastern State Transport University, 680021 Khabarovsk, Russia

6. Federal Research Center “Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences”, 660036 Krasnoyarsk, Russia

7. Siberian State University of Science and Technologies, 660037 Krasnoyarsk, Russia

Abstract

The influence of Bi2O3–MoO3–B2O3–Na2O flux components on the crystallization of the triple oxides (Mn,Fe,Ga)2O3is studied. 9 single crystal samples of bixbyite, spinel and orthorhombic phase are obtained and characterized.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CE/D3CE00147D

Reference37 articles.

1. Study of magnetic and magnetocaloric properties of La0.6Pr0.1Ba0.3MnO3 and La0.6Pr0.1Ba0.3Mn0.9Fe0.1O3 perovskite-type manganese oxides

2. Synthesis, Crystal Structure, Crystal Chemistry, and Magnetic Properties of PbMBO4 (M = Cr, Mn, Fe): A New Structure Type Exhibiting One- Dimensional Magnetism

3. Magnetic interactions in La0.7Sr0.3Mn1−Me O3 (Me=Ga, Fe, Cr) manganites

4. Impact of Mn3+ upon Structure and Magnetism of the Perovskite Derivative Pb2–xBaxFeMnO5 (x ∼ 0.7)

5. Growth and acoustic characteristics of α-Fe2−xGaxO3 single crystals

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