Photodissociation of CH2BrCHBrC(O)Cl at 248 nm: probing Br2 as the primary fragment using cavity ring-down spectroscopy

Author:

Balaganesh Muthiah1ORCID,Song Joseph2,Kasai Toshio13,Lin King-Chuen14ORCID

Affiliation:

1. Department of Chemistry, National Taiwan Univeristy, Taipei 106, Taiwan

2. Department of Chemistry, Stony Brook University, 100 Nicolls Road, Stony Brook, New York 11794-3400, USA

3. Institute of Scientific and Industrial Research, Osaka University, Ibaraki, Osaka 567-0047, Japan

4. Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan

Abstract

The photodissociation of 2,3-dibromopropionyl chloride (CH2BrCHBrC(O)Cl, 2,3-DBPC) at 248 nm was carried out to study Br2 as the primary molecular product in the B3Π+0u ← X1Σ+g transition using cavity ring-down absorption spectroscopy.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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