Nickel as a co-catalyst for photocatalytic hydrogen evolution on graphitic-carbon nitride (sg-CN): what is the nature of the active species?

Author:

Indra Arindam12345,Menezes Prashanth W.12345,Kailasam Kamalakannan678,Hollmann Dirk9105,Schröder Marc12345,Thomas Arne12345,Brückner Angelika9105,Driess Matthias12345

Affiliation:

1. Metalorganic Chemistry and Inorganic Materials

2. Department of Chemistry

3. Technische Universität Berlin

4. D-10623 Berlin

5. Germany

6. Institute of Nano Science and Technology

7. Mohali

8. India

9. Leibniz Institute for Catalysis at the University of Rostock

10. 18059 Rostock

Abstract

Structural changes of a nickel co-catalyst on graphitic carbon nitride have been uncovered during photocatalytic proton reduction by using XPS and in situ EPR measurements.

Funder

Bundesministerium für Bildung und Forschung

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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