Synthesis and coordination ability of a partially silicon based crown ether-Reference-Cited by-同舟云学术

Synthesis and coordination ability of a partially silicon based crown ether

Published:2016 Issue:90 Volume:52 Page:13265-13268
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Reuter Kirsten¹²³⁴⁵,Thiele Günther⁶⁷⁸⁹,Hafner Thomas¹⁰¹¹¹²¹³,Uhlig Frank¹⁰¹¹¹²¹³,von Hänisch Carsten¹²³⁴⁵

Affiliation:

1. Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW)

2. Philipps-Universität Marburg

3. Hans-Meerwein-Straße 4

4. 35043 Marburg

5. Germany

6. Department of Chemistry

7. University of California

8. Berkeley

9. USA

10. Institut für Anorganische Chemie

11. TU Graz

12. 6330 Graz

13. Austria

Abstract

The synthesis of the first hybrid crown ether with two adjacent disilane fragments is described. Coordination experiments and DFT calculation show a considerably higher complexation ability towards Li⁺ in comparison to [12]crown-4.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC07520G

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