Reactive polycyclic aromatic hydrocarbon dimerization drives soot nucleation
Author:
Affiliation:
1. Particle Technology Laboratory
2. Institute of Process Engineering
3. Department of Mechanical and Process Engineering
4. ETH Zürich
5. Zürich CH-8092
Abstract
Nucleation is an important yet poorly understood step in soot formation. Strong chemical bonds between PAH monomers are required as physical dimerization cannot explain soot formation at high temperatures. Dimers can be considered as soot nuclei as larger oligomers have negligible contribution.
Funder
Natural Sciences and Engineering Research Council of Canada
Eidgenössische Technische Hochschule Zürich
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CP/C7CP07803J
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