Structural and mechanistic basis for the high activity of Fe–N–C catalysts toward oxygen reduction

Author:

Li Jingkun1234,Ghoshal Shraboni1234,Liang Wentao5234,Sougrati Moulay-Tahar678910,Jaouen Frédéric678910,Halevi Barr11124,McKinney Samuel11124,McCool Geoff11124,Ma Chunrong1314151617,Yuan Xianxia1314151617,Ma Zi-Feng1314151617,Mukerjee Sanjeev1234,Jia Qingying1234

Affiliation:

1. Department of Chemistry and Chemical Biology

2. Northeastern University

3. Boston

4. USA

5. Department of Biology

6. Institut Charles Gerhardt Montpellier

7. UMR CNRS 5253

8. Université Montpellier

9. Agrégats

10. Interfaces et Matériaux pour l’Energie

11. Pajarito Powder, LLC (PPC)

12. Albuquerque

13. Shanghai Electrochemical Energy Devices Research Center

14. Department of Chemical Engineering

15. Shanghai Jiao Tong University

16. Shanghai 200240

17. People's Republic of China

Abstract

The biomimetic dynamic nature of the Fe–N–C active site with a near-optimal Fe2+/3+redox potential facilitates ORR by balancing the site-blocking effect and O2dissociation.

Funder

Office of Energy Efficiency and Renewable Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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