Synthesis, band structure and photocatalytic properties of Sillén–Aurivillius oxychlorides BaBi5Ti3O14Cl, Ba2Bi5Ti4O17Cl and Ba3Bi5Ti5O20Cl with triple-, quadruple- and quintuple-perovskite layers

Author:

Ozaki Daichi12345ORCID,Suzuki Hajime12345ORCID,Ogawa Kanta12345ORCID,Sakamoto Ryota12345ORCID,Inaguma Yoshiyuki67895ORCID,Nakashima Kouichi101112135,Tomita Osamu12345ORCID,Kageyama Hiroshi12345ORCID,Abe Ryu12345ORCID

Affiliation:

1. Department of Energy and Hydrocarbon Chemistry

2. Graduate School of Engineering, Katsura

3. Kyoto University

4. Kyoto 615-8510

5. Japan

6. Department of Chemistry

7. Faculty of Science

8. Gakushuin University

9. Tokyo 171-8588

10. Department of Materials Science and Engineering

11. Graduate School of Science and Engineering

12. Ibaraki University

13. Hitachi

Abstract

New Sillén–Aurivillius layered oxychlorides with triple-, quadruple- and quintuple-perovskite layers (n = 3−5) are successfully synthesized and their photocatalytic activities are enhanced with increasing the number of the perovskite layers.

Funder

Japan Society for the Promotion of Science

Core Research for Evolutional Science and Technology

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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