Dehydrocoupling of dimethylamine–borane promoted by manganese(ii) m-terphenyl complexes
Author:
Affiliation:
1. School of Chemistry
2. University of Nottingham
3. University Park
4. Nottingham
5. UK
6. Nanoscale and Microscale Research Centre
Abstract
Low-coordinate m-terphenyl complexes are precatalysts for dehydrocoupling of dimethylamine–borane, where small changes in coordination environment effect significant mechanistic differences.
Funder
Leverhulme Trust
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CY/C7CY02086D
Reference53 articles.
1. Combining Protons and Hydrides by Homogeneous Catalysis for Controlling the Release of Hydrogen from Ammonia–Borane: Present Status and Challenges
2. Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials
3. Ammonia-Borane and Related Compounds as Dihydrogen Sources
4. Amine− and Phosphine−Borane Adducts: New Interest in Old Molecules
5. Mechanism of Metal-Free Hydrogen Transfer between Amine–Boranes and Aminoboranes
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