Al(ORF)3 (RF = C(CF3)3) activated silica: a well-defined weakly coordinating surface anion-Reference-Cited by-同舟云学术

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Al(ORF)3 (RF = C(CF3)3) activated silica: a well-defined weakly coordinating surface anion

Published:2020 Issue:6 Volume:11 Page:1510-1517
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Culver Damien B.¹²³⁴,Venkatesh Amrit¹⁵⁶⁴^ORCID,Huynh Winn¹²³⁴,Rossini Aaron J.¹⁵⁶⁴^ORCID,Conley Matthew P.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of California

3. Riverside

4. USA

5. Iowa State University

6. Ames

Abstract

A strong Lewis acid coordinates to silanols on silica to form a strong acid, which acts as a weakly coordinating anion when deprotonated.

Funder

National Science Foundation

American Chemical Society Petroleum Research Fund

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/C9SC05904K

Reference71 articles.

1. Noncoordinating Anions—Fact or Fiction? A Survey of Likely Candidates

2. G. A. Olah , G. K.Surya Prakash , Á.Molnár and J.Sommer , in Superacid Chemistry , John Wiley & Sons, Inc. , 2008 , ch. 1, pp. 1–34 , 10.1002/9780470421604

3. Reactive cationic dicyclopentadienyl zirconium(IV) complexes

4. The Silylium Ion Problem, R3Si+. Bridging Organic and Inorganic Chemistry

5. Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure−Activity Relationships

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