Steric effects in light-induced solvent proton abstraction

Author:

Lahiri Jurick1234ORCID,Moemeni Mehdi1234,Magoulas Ilias1234ORCID,Yuwono Stephen H.1234ORCID,Kline Jessica1234,Borhan Babak1234ORCID,Piecuch Piotr12345ORCID,Jackson James E.1234ORCID,Blanchard G. J.1234ORCID,Dantus Marcos12345ORCID

Affiliation:

1. Department of Chemistry

2. Michigan State University

3. East Lansing

4. USA

5. Department of Physics and Astronomy

Abstract

The significance of solvent structural factors in the excited-state proton transfer reactions of the super photobase FR0-SB with alcohols is examined using steady-state and time-resolved spectroscopy and quantum chemistry computations.

Funder

Defense Advanced Research Projects Agency

National Science Foundation

National Institutes of Health

U.S. Department of Energy

Aviation and Missile Research, Development, and Engineering Center

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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