Enantioselective total syntheses of (−)-cephalotaxine and (−)-amathaspiramide F through a key Ir/Cu dual catalysis-Reference-Cited by-同舟云学术

Enantioselective total syntheses of (−)-cephalotaxine and (−)-amathaspiramide F through a key Ir/Cu dual catalysis

Published:2023 Issue:10 Volume:10 Page:2532-2537
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Sheng Peng-Zhen¹²,Li Lu-Lu³²,Zhang Hongbin¹^ORCID,Wei Kun²,Yang Yu-Rong²^ORCID

Affiliation:

1. Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, Yunnan Provincial Centre for Research and Development of Natural Products, School of Chemical Science and Technology, Yunnan University, Kunming, 650091, China

2. State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming 650201, China

3. School of Life Sciences, Yunnan University, Kunming, 650091, China

Abstract

Ir/Cu dual-catalysed allylation constructs vicinal tertiary and N-substituted quaternary stereogenic centres of two alkaloids in a single operation.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00233K

Reference53 articles.

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3. J.Perard-Viret , L.Quteishat , R.Alsalim , J.Royer and F.Dumas , Cephalotaxus alkaloids , in The Alkaloids , ed. H.-J. Knolker , Elsevier , San Diego , 2017 , vol. 78 , pp. 205–352

4. Recent Total Syntheses of Cephalotaxine‐Type Alkaloids (2016–2021)

5. Total synthesis of cephalotaxine

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