Remote carbamate-directed site-selective benzylic C–H oxygenation <i>via</i> synergistic copper/TEMPO catalysis at room temperature-Reference-Cited by-同舟云学术

Remote carbamate-directed site-selective benzylic C–H oxygenation via synergistic copper/TEMPO catalysis at room temperature

Published:2022 Issue:12 Volume:9 Page:3169-3178
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Chen Jiaming¹,Wang Fang¹,Huang Yanping¹²,Jia Xiaoqi¹,Zhuang Dailin¹,Wan Zhenyang¹,Li Ziyuan¹^ORCID

Affiliation:

1. Department of Pharmaceutical and Biological Engineering, School of Chemical Engineering, Sichuan University, Chengdu 610065, China

2. Engineering Experimental Teaching Centre, School of Chemical Engineering, Sichuan University, Chengdu 610065, China

Abstract

A benzylic C(sp3)–H oxygenation with water at room temperature through a ligand- and additive-free synergistic copper/TEMPO-catalysed radical relay pathway and a remote directing strategy is described.

Funder

National Natural Science Foundation of China

Department of Science and Technology of Sichuan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO00435F

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