Synthesis, structure, and magnetic properties of diamagnetic Co(<scp>iii</scp>) ion-based heterometallic Co<sup>III</sup>–Ln<sup>III</sup> (Ln = Dy, Tb, Ho, Er) complexes-Reference-Cited by-同舟云学术

Synthesis, structure, and magnetic properties of diamagnetic Co(iii) ion-based heterometallic Co^III–Ln^III (Ln = Dy, Tb, Ho, Er) complexes

Published:2024 Issue: Volume: Page:
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Barman Nandini¹,Halder Purbashree¹,Mukhopadhyay Subrata¹,Schwarz Björn²^ORCID,Colacio Enrique³^ORCID,Rana Rajanikanta⁴,Rajaraman Gopalan⁴,Goura Joydeb¹⁵⁶^ORCID

Affiliation:

1. Department of Chemistry, Jadavpur University, Kolkata 700032, India

2. Karlsruhe Institute of Technology (KIT) – Institute for Applied Materials (IAM), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

3. Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, Av. Fuentenueva S/N, 18071 Granada, Spain

4. Department of Chemistry, Indian Institute of Technology, Bombay, Powai, Mumbai, Maharashtra 400076, India

5. Department of Chemistry, University of Delhi, Delhi 110007, India

6. Department of Chemistry, Bangabasi College, Kolkata 700009, India

Abstract

A series of heterometallic dinuclear complexes [CoIIILnIII(L)(μ-Piv)2(Piv)2(OHMe)2] (LnIII = Dy, Tb, Ho and Er) are reported. Experimental magnetic studies and theoretical calculations indicate that Dy(iii) shows slow relaxation at low temperature.

Funder

Science and Engineering Research Board

Jadavpur University

University of Delhi

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ02058H

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