Two alternative approaches to access mixed hydride-amido zinc complexes: synthetic, structural and solution implications
Author:
Affiliation:
1. WestCHEM
2. Department of Pure and Applied Chemistry
3. University of Strathclyde
4. Glasgow
5. UK
6. School of Chemistry
7. Newcastle University
8. Newcastle upon Tyne
Abstract
In the presence of a bulky N-heterocyclic carbene, Zn(HMDS)2can be converted in to either a mononuclear amido/hydride complex or a tetranuclear hydride rich cluster depending on the hydride source and reaction conditions employed.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00312A
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