DFT characterization on the mechanism of sulfoxidation with H2O2catalyzed by tetranuclear peroxotungstates [XO4{WO(O2)2}4]n−(X = SiIV, PV, SVI, AsV, and SeVI)-Reference-Cited by-同舟云学术

DFT characterization on the mechanism of sulfoxidation with H2O2catalyzed by tetranuclear peroxotungstates [XO4{WO(O2)2}4]n−(X = SiIV, PV, SVI, AsV, and SeVI)

Published:2015 Issue:19 Volume:44 Page:9063-9070
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhu Bo¹²³⁴⁵,Yan Li-Kai¹²³⁴⁵,Guan Wei¹²³⁴⁵,Su Zhong-Min¹²³⁴⁵

Affiliation:

1. Institute of Functional Material Chemistry

2. Faculty of Chemistry

3. Northeast Normal University

4. Changchun 130024

5. P. R. China

Abstract

Tetranuclear peroxotungstates exhibit highly efficient sulfoxidation. DFT calculations disclose the mechanism of sulfoxidation with H₂O₂catalyzed by [XO₄{WO(O₂)₂}₄]ⁿ⁻(X = Si^IV, P^V, S^VI, As^V, and Se^VI).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00318K

Reference66 articles.

1. Applications of Sulfoxides to Asymmetric Synthesis of Biologically Active Compounds

2. Biomimetic Synthesis of Lantibiotics

3. Esomeprazole

4. Rearrangements of sulfoxides and sulfones in the total synthesis of natural compounds

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