A chiral organic base catalyst with halogen-bonding-donor functionality: asymmetric Mannich reactions of malononitrile with N-Boc aldimines and ketimines-Reference-Cited by-同舟云学术

A chiral organic base catalyst with halogen-bonding-donor functionality: asymmetric Mannich reactions of malononitrile with N-Boc aldimines and ketimines

Published:2018 Issue:31 Volume:54 Page:3847-3850
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kuwano Satoru¹²³⁴⁵,Suzuki Takumi¹²³⁴⁵,Hosaka Yusei¹²³⁴⁵,Arai Takayoshi¹²³⁴⁵^ORCID

Affiliation:

1. Soft Molecular Activation Research Center (SMARC)

2. Chiba Iodine Resource Innovation Center (CIRIC)

3. Molecular Chirality Research Center (MCRC), and Department of Chemistry

4. Graduate School of Science

5. Chiba University

Abstract

Asymmetric Mannich reactions of malononitrile with various N-Boc imines were developed using a chiral organic base catalyst with halogen-bonding-donor functionality.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC00865E

Reference54 articles.

1. Nucleophilic Chiral Amines as Catalysts in Asymmetric Synthesis

2. Asymmetric Enamine Catalysis

3. Enantioselective Michael Reaction of Malonates to Nitroolefins Catalyzed by Bifunctional Organocatalysts

4. The Halogen Bond

5. Halogen bonding in solution: thermodynamics and applications

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