Luminescence quenching in epitaxially grown PCN-224 type metal–organic frameworks

Author:

Burger Tobias1,Velásquez-Hernández Miriam de J.2ORCID,Saf Robert3,Borisov Sergey M.1ORCID,Slugovc Christian3ORCID

Affiliation:

1. Graz University of Technology, Institute of Analytical Chemistry and Food Chemistry, Stremayrgasse 9, 8010, Graz, Austria

2. Graz University of Technology, Institute of Physical and Theoretical Chemistry, Stremayrgasse 9, 8010, Graz, Austria

3. Graz University of Technology, Institute for Chemistry and Technology of Materials, Stremayrgasse 9, 8010, Graz, Austria

Abstract

Probing core–shell and multivariant MOFs of the PCN-224 type prepared from metal-free and metalated porphyrin building blocks with luminescence quenching upon exposure to oxygen reveals oxygen quenching to occur also in the core of the MOF.

Funder

Technische Universität Graz

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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