Synthesis and characterization of carbene derivatives of Th@C3v(8)-C82 and U@C2v(9)-C82: exceptional chemical properties induced by strong actinide–carbon cage interaction-Reference-Cited by-同舟云学术

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Synthesis and characterization of carbene derivatives of Th@C3v(8)-C82 and U@C2v(9)-C82: exceptional chemical properties induced by strong actinide–carbon cage interaction

Published:2021 Issue:7 Volume:12 Page:2488-2497
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Liu Xinye¹²³⁴,Li Bo⁵⁶⁷⁴,Yang Wei¹²³⁴,Yao Yang-Rong⁸⁹¹⁰¹¹,Yang Le⁵⁶⁷⁴,Zhuang Jiaxin¹²³⁴,Li Xiaomeng¹²³⁴,Jin Peng⁵⁶⁷⁴^ORCID,Chen Ning¹²³⁴^ORCID

Affiliation:

1. College of Chemistry, Chemical Engineering and Materials Science

2. Soochow University

3. Suzhou

4. P. R. China

5. School of Materials Science and Engineering

6. Hebei University of Technology

7. Tianjin 300130

8. Department of Chemistry

9. University of Texas at El Paso

10. El Paso

11. USA

Abstract

Photochemical reaction of Th@C_3v(8)-C₈₂ and U@C_2v(9)-C₈₂ with 2-adamantane-2,3′-[3H]-diazirine (AdN₂, 1) afforded three isomers of Th@C_3v(8)-C₈₂Ad and four isomers of U@C_2v(9)-C₈₂Ad (Ad = adamantylidene), respectively.

Funder

Natural Science Foundation of Hebei Province

Natural Science Foundation of Jiangsu Province

Priority Academic Program Development of Jiangsu Higher Education Institutions

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06111E

Reference47 articles.

1. Endohedral Fullerenes

2. Single Molecule Magnetism with Strong Magnetic Anisotropy and Enhanced Dy∙∙∙Dy Coupling in Three Isomers of Dy‐Oxide Clusterfullerene Dy 2 O@C 82

3. Nonionic Sc3N@C80 Dopant for Efficient and Stable Halide Perovskite Photovoltaics

4. Recent Progress of Molecular Imaging Probes Based on Gadofullerenes

5. Exohedral functionalization of endohedral metallofullerenes: Interplay between inside and outside

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