Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”-Reference-Cited by-同舟云学术

Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”

Published:2021 Issue:10 Volume:12 Page:3682-3692
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Osipova Elena S.¹²³⁴,Gulyaeva Ekaterina S.¹²³⁴,Gutsul Evgenii I.¹²³⁴,Kirkina Vladislava A.¹²³⁴,Pavlov Alexander A.¹²³⁴^ORCID,Nelyubina Yulia V.¹²³⁴,Rossin Andrea⁵⁶⁷^ORCID,Peruzzini Maurizio⁵⁶⁷^ORCID,Epstein Lina M.¹²³⁴,Belkova Natalia V.¹²³⁴^ORCID,Filippov Oleg A.¹²³⁴^ORCID,Shubina Elena S.¹²³⁴^ORCID

Affiliation:

1. A.N. Nesmeyanov Institute of Organoelement Compounds

2. Russian Academy of Sciences (INEOS RAS)

3. 119991 Moscow

4. Russia

5. Istituto di Chimica dei Composti Organometallici – Consiglio Nazionale delle Ricerche (ICCOM – CNR)

6. Sesto Fiorentino

7. Italy

Abstract

Bimetallic complexes [LW(CO)₂(μ-CO)⋯Pd(PCP)] cooperatively activate amine-boranes for their dehydrogenation via N–H proton tunneling at RDS and H₂ evolution from two neutral hydrides.

Funder

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Consiglio Nazionale delle Ricerche

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06114J

Reference60 articles.