Molecular rigidity and enthalpy–entropy compensation in DNA melting
Author:
Affiliation:
1. Materials Science and Engineering Division
2. National Institute of Standards and Technology
3. Gaithersburg
4. USA
5. Departments of Physics and Molecular Biology & Biochemistry
6. Wesleyan University
7. Middletown
Abstract
Enthalpy–entropy compensation is observed in diverse molecular binding processes of importance to living systems and manufacturing applications. We suggest that variations in molecular rigidity might provide a common origin of this phenomenon in the binding of complex molecules such as DNA.
Funder
National Institute of Standards and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/SM/C7SM01220A
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