Activation of olefin metathesis complexes containing unsymmetrical unsaturated N-heterocyclic carbenes by copper and gold transmetalation

Author:

Kamal Fadwa12345ORCID,Colombel-Rouen Sophie12345ORCID,Dumas Adrien12345,Guégan Jean-Paul12345,Roisnel Thierry12345ORCID,Dorcet Vincent12345ORCID,Baslé Olivier12345ORCID,Rouen Mathieu6785ORCID,Mauduit Marc12345ORCID

Affiliation:

1. Univ. Rennes

2. Ecole Nationale Supérieure de Chimie de Rennes

3. CNRS, ISCR – UMR 6226

4. F-35000 Rennes

5. France

6. DEMETA SAS

7. 6 rue Pierre-Joseph Colin

8. 35000 Rennes

Abstract

The activation of latent ruthenium complexes containing two unsymmetrical NHCs by copper and gold transmetalation leads to impressive initiation rates in olefin metathesis.

Funder

Association Nationale de la Recherche et de la Technologie

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference23 articles.

1. Handbook of Metathesis , ed. R. H. Grubbs , A. G. Wenzel , D. J. O’Leary and E. Khosravi , 2nd edn, Wiley-VCH , Weinheim, Germany , 2015

2. Ring-opening metathesis polymerization (ROMP) of norbornene by a Group VIII carbene complex in protic media

3. Olefin Metathesis: Theory and Pratice , ed. K. Grela , Wiley-VCH , Weinheim, Germany , 2014

4. Synthesis and Activity of a New Generation of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with 1,3-Dimesityl-4,5-dihydroimidazol-2-ylidene Ligands

5. Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts

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