Role of Ga3+ promoter in the direct synthesis of iso-butanol via syngas over a K–ZnO/ZnCr2O4 catalyst-Reference-Cited by-同舟云学术

Role of Ga3+ promoter in the direct synthesis of iso-butanol via syngas over a K–ZnO/ZnCr2O4 catalyst

Published:2021 Issue:3 Volume:11 Page:1077-1088
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Zhang Tao¹²³⁴⁵,Zeng Chunyang⁶⁷⁵,Wu Yingquan¹²³⁴⁵,Gong Nana¹²³⁴⁵^ORCID,Yang Jiaqian¹²³⁴⁵,Yang Guohui¹²³⁴⁵,Tsubaki Noritatsu⁸⁹¹⁰¹¹¹²^ORCID,Tan Yisheng¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Coal Conversion

2. Institute of Coal Chemistry

3. Chinese Academy of Science

4. Taiyuan

5. China

6. China Petroleum Chemical Industry Federation

7. Beijing 100723

8. Department of Applied Chemistry

9. School of Engineering

10. University of Toyama

11. Toyama

12. Japan

Abstract

ZG, gallium cluster and ZnGa₂O₄ were formed by introducing Ga³⁺ to K–ZnO/ZnCr₂O₄ iso-butanol catalyst. Only a moderate amount of ZG promotes the space time yield (STY) and selectivity of alcohols for iso-butanol synthesis.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D0CY01688H

Reference63 articles.

1. Active Centers of Catalysts for Higher Alcohol Synthesis from Syngas: A Review

2. Reaction Condition Optimization and Lumped Kinetics Study for Lower Alcohols Synthesis from Syngas Using a Two-Stage Bed Catalyst Combination System

3. Recent developments in isobutanol synthesis from synthesis gas