Trends in the stability of covalent dative bonds with variable solvent polarity depend on the charge transfer in the Lewis electron-pair system-Reference-Cited by-同舟云学术

Trends in the stability of covalent dative bonds with variable solvent polarity depend on the charge transfer in the Lewis electron-pair system

Published:2023 Issue:38 Volume:25 Page:25961-25964
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Lo Rabindranath¹²^ORCID,Manna Debashree¹,Miriyala Vijay Madhav¹²,Nachtigallová Dana¹³,Hobza Pavel¹³^ORCID

Affiliation:

1. Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, v.v.i., Flemingovo nám. 2, Prague 6 16000, Czech Republic

2. Regional Centre of Advanced Technologies and Materials, Czech Advanced Technology and Research Institute, Palacký University Olomouc, Křížkovského 511/8, Olomouc 77900, Czech Republic

3. IT4Innovations, VŠB-Technical University of Ostrava, 17. listopadu 2172/15, Ostrava-Poruba 70800, Czech Republic

Abstract

Depending upon the extent of charge transfer between the subsystems, the neutral dative bond complexes may stabilise or destabilise with increase in solvent polarity.

Funder

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP03445C

Reference15 articles.

1. History and Future of Dative Bonds

2. How Strong is a Reverse Dative Bond? Compliance Constants as Unique Bond Strength Descriptors

3. Covalent and Ionic Nature of the Dative Bond and Account of Accurate Ammonia Borane Binding Enthalpies

4. Femtosecond dynamics of dative bonding: Concepts of reversible and dissociative electron transfer reactions

5. The stability of covalent dative bond significantly increases with increasing solvent polarity

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