Switching of the reaction enthalpy from exothermic to endothermic for decomposition of H2CO3 under confinement-Reference-Cited by-同舟云学术

Switching of the reaction enthalpy from exothermic to endothermic for decomposition of H2CO3 under confinement

Published:2019 Issue:37 Volume:21 Page:20849-20856
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Mallick Subhasish¹²³⁴^ORCID,Kumar Pradeep¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Malaviya National Institute of Technology Jaipur

3. Jaipur

4. India

Abstract

Various size fullerenes (C₆₀, C₇₀ and C₈₄) have been used as a means of confinement to study the decomposition reaction of carbonic acid alone as well as in the presence of a single water molecule in a confined environment.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP04587B

Reference61 articles.

1. o-Benzyne: Strained Alkyne or Cumulene?—NMR Characterization in a Molecular Container

2. Photochemical and Thermal Reactions of Intermediates in the Phenylnitrene Rearrangement Inside a Hemicarcerand

3. First innermolecular Diels–Alder reaction of o-benzyne inside a molecular container compound

4. The Taming of Cyclobutadiene

5. Effects of nanoconfinement on the morphology and reactivity of organic materials

Cited by 12 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Chemical reactivity inside carbon cages: theoretical insights from a fullerene confinement;Theoretical Chemistry Accounts;2024-08-17

2. Estimation of effective diffusivity, thermodynamic parameter and drying kinetics exploration in coffee berries drying;Reaction Kinetics, Mechanisms and Catalysis;2023-05-08

3. How an electric field makes endohedral fullerene an improved catalyst for hydrogen evolution reaction;Computational and Theoretical Chemistry;2023-03

4. External electric field to control the Diels–Alder reactions of endohedral fullerene;Physical Chemistry Chemical Physics;2022

5. Can water molecules bind by the oxygen oxygen covalent bond? A confinement induced bonding;Computational and Theoretical Chemistry;2021-12