Impact of medium-pore zeolite topology on para-xylene production from toluene alkylation with methanol

Author:

Parmar Deependra1ORCID,Cha Seung Hyeok12ORCID,Huang Chenfeng1,Chiang Hsu3,Washburn Seth3,Grabow Lars C.14ORCID,Rimer Jeffrey D.1ORCID

Affiliation:

1. William A. Brookshire Department of Chemical and Biomolecular Engineering, University of Houston, 4226 Martin Luther King Boulevard, Houston, Texas 77204, USA

2. Green Carbon Research Center, Korea Research Institute of Chemical Technology (KRICT), 141 Gajeongro, Yuseong, Daejeon 34114, Republic of Korea

3. ExxonMobil Technology and Engineering, 5200 Bayway Drive, Baytown, Texas 77520, USA

4. Texas Center for Superconductivity at the University of Houston, 3369 Cullen Blvd., Houston, TX 77204, USA

Abstract

This study compares seven different medium-pore zeolites as catalysts for toluene alkylation with methanol, revealing the superior performance of MCM-22 at high pressure is attributed to coke accumulation, contrary to conventional expectations.

Funder

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference54 articles.

1. F.Alario and M.Guisnet , Para-xylene manufacturing: catalytic reactions and processes, Zeolites for Cleaner Technologies , 2002 , pp. 189–207

2. Process of p-Xylene Production by Highly Selective Methylation of Toluene

3. A review of advances in production and separation of xylene isomers

4. P.Wantanachaisaeng and K.O'Neil , Capturing opportunities for para-xylene production , UOP LLC , 2007

5. Global S. P. , Para Xylene, Chemical Economics Handbook , 2021 , pp. 1–106

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