Metal–carbon bonding in early lanthanide substituted cyclopentadienyl complexes probed by pulsed EPR spectroscopy-Reference-Cited by-同舟云学术

Metal–carbon bonding in early lanthanide substituted cyclopentadienyl complexes probed by pulsed EPR spectroscopy

Published:2024 Issue:8 Volume:15 Page:3003-3010
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Nodaraki Lydia E.¹²,Liu Jingjing¹,Ariciu Ana-Maria¹²,Ortu Fabrizio¹^ORCID,Oakley Meagan S.¹^ORCID,Birnoschi Letitia¹,Gransbury Gemma K.¹^ORCID,Cobb Philip J.¹,Emerson-King Jack¹^ORCID,Chilton Nicholas F.¹^ORCID,Mills David P.¹^ORCID,McInnes Eric J. L.¹²,Tuna Floriana¹²^ORCID

Affiliation:

1. Department of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK

2. Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK

Abstract

We report relaxation and ligand hyperfine effects in an isostructural series of early lanthanide substituted cyclopentadienyl complexes, [Ln(Cptt)3] (Ln = Ce, Nd, Sm; Cptt = C5H3tBu2-1,3), by pulsed EPR spectroscopy.

Funder

Natural Sciences and Engineering Research Council of Canada

H2020 Marie Skłodowska-Curie Actions

China Scholarship Council

Engineering and Physical Sciences Research Council

H2020 European Research Council

Royal Society

Marie Curie

Ministry of Defence

University of Manchester

Publisher

Royal Society of Chemistry (RSC)