CO2 activation by copper oxide clusters: size, composition, and charge state dependence

Author:

Mikolaj Pavol1ORCID,Zamora Yusti Barbara2ORCID,Nyulászi László23ORCID,Bakker Joost M.4ORCID,Höltzl Tibor35ORCID,Lang Sandra M.1ORCID

Affiliation:

1. Institute of Surface Chemistry and Catalysis, University of Ulm, Ulm 89069, Germany

2. Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Műegytem rkp. 3, Budapest-1111, Hungary

3. HUN-REN-BME Computation Driven Chemistry research group, Műegytem rkp. 3, Budapest-1111, Hungary

4. Radboud University, Institute of Molecules and Materials, FELIX Laboratory, 6525 ED, Nijmegen, The Netherlands

5. Furukawa Electric Institute of Technology, Nanomaterials Science Group, Késmárk utca 28/A, Budapest 1158, Hungary

Abstract

Infrared multiple-photon dissociation (IR-MPD) spectroscopy and density functional theory (DFT) calculations reveal a strongly charge dependent activation of CO2 by copper oxide clusters.

Funder

Laserlab-Europe

HORIZON EUROPE Marie Sklodowska-Curie Actions

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Magyar Tudományos Akadémia

Publisher

Royal Society of Chemistry (RSC)

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