The modulation mechanism of geometric and electronic structures of bimetallic catalysts: Pd13−mAgm (m=0–13) clusters for acetylene semi-hydrogenation-Reference-Cited by-同舟云学术

The modulation mechanism of geometric and electronic structures of bimetallic catalysts: Pd_13−mAg_m (m=0–13) clusters for acetylene semi-hydrogenation

Published:2022 Issue:20 Volume:9 Page:5169-5180
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Wei Panpeng¹,Zheng Jian¹,Li Qiang²,Qin Yucai²,Guan Huimin²,Tan Duping³,Song Lijuan¹²^ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering, China University of Petroleum, Qingdao, Shandong 266580, China

2. Key Laboratory of Petrochemical Catalytic Science and Technology, Liaoning Province, Liaoning Petrochemical University, Fushun, Liaoning 113001, China

3. Lanzhou Petrochemical Research Center, Petrochemical Research Institute, Petrochina, Lanzhou 730060, China

Abstract

The modulation mechanism of the second metal in bimetallic catalysts is examined by taking acetylene semi-hydrogenation over Pd13−mAgm clusters, in which a metastable Pd6Ag7 structure exhibits excellent activity/selectivity to ethylene.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Liaoning Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI01222G

Reference54 articles.

1. Bimetallic catalysts; application in catalytic reforming

2. Designing bimetallic catalysts for a green and sustainable future

3. Bimetallic catalysts for hydrogen generation

4. Synthetic strategies of supported atomic clusters for heterogeneous catalysis

5. Bimetallic palladium catalysts: influence of the co-metal on the catalyst performance

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