Lithium insertion in hard carbon as observed by 7Li NMR and XRD. The local and mesoscopic order and their relevance for lithium storage and diffusion

Author:

Fang Yuan1,Peuvot Kevin2,Gratrex Alice2ORCID,Morozov Evgeny V.1,Hagberg Johan2ORCID,Lindbergh Göran2ORCID,Furó István1ORCID

Affiliation:

1. Division of Applied Physical Chemistry, Department of Chemistry, KTH Royal Institute of Technology, SE-100 44, Stockholm, Sweden

2. Division of Applied Electrochemistry, Department of Chemical Engineering, KTH Royal Institute of Technology, SE-100 44, Stockholm, Sweden

Abstract

The storage mechanism of lithium in hard carbon was investigated by 7Li NMR and 2D-XRD methods. Lithium was found to fill disordered sites first and then fill the ordered sites of graphitic character arranged in a distinct mesoscopic order.

Funder

Energimyndigheten

Stiftelsen för Strategisk Forskning

Deutsches Elektronen-Synchrotron

Vetenskapsrådet

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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