Molybdenum complexes with a μ-O{MoO2}2 core: their synthesis, crystal structure and application as catalysts for the oxidation of bicyclic alcohols using N-based additives
Author:
Affiliation:
1. Department of Chemistry
2. Indian Institute of Technology Roorkee
3. Roorkee 247667
4. India
5. Departamento de Química Fundamental
6. Universidade da Coruña
7. Campus de A Zapateira
8. 15071 A Coruña
9. Spain
Abstract
Binuclear molybdenum(vi) complexes with a μ-O{MoO2}2 core as catalysts for the oxidation of bicyclic alcohols (fenchyl alcohol and isoborneol), using 30% H2O2 as the oxidant in the presence of NEt3 as the additive, are reported.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C6NJ03162E
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4. Oxoperoxo molybdenum(VI)- and tungsten(VI) complexes with 1-(2′-hydroxyphenyl) ethanone oxime: Synthesis, structure and catalytic uses in the oxidation of olefins, alcohols, sulfides and amines using H2O2 as a terminal oxidant
5. Synthesis, X-ray structure and oxidation catalysis of a oxido–peroxido molybdenum(VI) complex with a tridentate Schiff base ligand
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